| Document Date: 2006-06-20 06:06:03
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City R1 MeMgBr / New York / / Company Boc / Bu3N R 2 2 2 1 1 LDA / Sumitomo Chemical / TMS / OMe i-Pr2NEt 1 1 R CO / OTBS / TBDMS / / Currency pence / / IndustryTerm bulk chemicals syntheses / active natural products / present protocol / metal enolates / basic media / pharmaceuticals / toxic metal reagents / thermodynamic controlled products / metabolic and chemical stability / chemicals / natural products / / Position rt / representative / General / / Product SiOTfs / ROH ROSi / TiCl4 - AcOEt / TiCl4 / / PublishedMedium the Nippon Keizai news / / TVStation TfO / / Technology Condensation / present protocol / This protocol / /
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Development of Efficient and Practical Ti-Claisen Condensation and the Related Aldol Reaction Ti(Zr)-Claisen condensations, Ti-direct aldol additions, related catalytic Claisen condensation have been applied for efficient and practical syntheses of useful fine chemicals and biologically active natural products. These protocols are new avenues for the