Weinheim / Wallingford / Abbott / Bristol / New York / /
Company
DuPont / Merck / Au Ag / Amgen / ACS / Gaussian Inc. / M. P. Stoykovich A. E. / Bristol-Myers Squibb / Boc / /
Country
Germany / United States / /
Currency
pence / / /
Facility
Princeton University / National Institute / /
IndustryTerm
metal / desired b-aryl aldehyde product / high-energy light promoted example / quaternary carbon-containing b-aryl products / metal nanomaterials / photoredox arylation protocol / transition metal catalysis / high-energy photochemistry / b-aryl products / high-energy / arylation protocol / lower energy / metal-to-ligand charge transfer / synergistic catalysis protocol / arylation products / /
Organization
U.S. Department of Energy / National Institute / National Science Foundation / Center for Catalysis / Division of Chemical Sciences / Princeton University / Henry Dreyfus Foundation / office of Basic Energy Science / Department of Chemistry / /
Person
David B. C. Martin / Danica A. Rankic / Nat / E. J. Walker Jr. / Michael T. Pirnot / P. Van Duyne / /
REPORTS off) the reaction rate steadily increases, and the PO selectivity steadily decreases, as a function of temperature. This behavior is fundamentally different than the behavior observed in response to light (Fig. 1