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Nathan S. Lewis*† and Daniel G. Nocera†‡ *Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, CA 91125; and ‡Department of Chemistry, Massachusetts Institute of Technolog
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Si / Williams / Hoffert / Bondin / Pasadena / New York / Washington / DC / Weinheim / Cambridge / /

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Stanford University / California Institute of Technology / reactor Lewis / Massachusetts Institute of Technology / /

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active site / solar device / energy demand / carbon-neutral solar energy storage / fossil energy resources / reactor technology / carbon-neutral energy / bonded metal / fossil-derived energy / renewable energy sources / sustainable energy production / solar thermal technology / solar energy resource / engineered systems / natural gas / oil and gas / energy sources / end-use chain / carbonneutral energy production / metal alkylidenes / energy supply / chemical bond-forming functions / large untapped solar energy resource / sustainable energy / energy inputs / average energy consumption rate / solar-converted energy / cellulosic conversion technology / conventional and unconventional oil reserves / energy / electricity price / metal / energy intensity / energy source / energy capture / energy consumption / metal oxo species / increased energy efficiency / gross domestic product / fossil energy base / least carbon-intensive fossil energy source / metal complex / present-day energy supply / energy statistics / desired chemical bond conversions / solar energy utilization / food crops / enduse chain / equal parts oil / energy losses / high-valent metal / converted energy / high-value energy / metal complexes / manufacturing paradigm / carbon-neutral energy needs / carbon-neutral energy production / energy problem / renewable energy resources / energy distribution / chemical bonds / carbon-free energy / solar energy conversion system / carbon-neutral energy system / desired chemical reactions / ample fossil energy reserves / Present photon conversion devices / average energy intensity / gas resources / solar electricity / energy conversion efficiency / Energy security / metal centers / carrier thermalization / renewable energy / sacrificial chemical reductants / present energy conversion efficiencies / paint / oil / metal oxos / energy consumption rate / energy mix / artificial photosynthetic systems / energy consequence / energy options / molecular systems / fossil energy / yearly averaged energy conversion / energy utilization / energy production / technology development and兾or policy / solar electricity modules / excess energy / metal-oxo species / electricity / printing / energy breakeven point / wireless current / delivered solar electricity / estimated fossil energy resources / energy conversion / mononuclear and binuclear metal complexes / electrical energy / electricity production / metal center / metal-based platform / transportation uses / solar energy / gas shift reaction / captured solar energy / chemical / energy crops / averaged energy intensity / /

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U.S. Department of Energy / Massachusetts Institute of Technology / Department of Chemistry / United Nations Environment Program / United Nations Development Program / Division of Chemistry and Chemical Engineering / office of Basic Energy Sciences / California Institute of Technology / National Science Foundation / National Academy of Sciences / Energy Information Administration / United Nations / World Meteorological Organization / Stanford University / /

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Daniel G. Nocera / Wilson SR / Nathan S. Lewis / Winkler JR / /

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Stanford University / /

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quantum dots / semiconductors / biofuels / Recombination / cellulosic conversion technology / semiconductor / reactor technology / fuel cell / solar thermal technology / PV technologies / simulation / /

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www.pnas.org兾cgi兾doi兾10.1073兾pnas.0603395103 / /

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