Mechanistic / Cl OC Mo OC CO / R Ph Ph Ph R CO / H Ph CO / Me3Si OC Me Mn CO CO / H O Steroid / TMSCl OC Mn Cl CO / H Br H H Br LDA / Metal Vinylidene Formation / L (CO)4W Ph H H CO / /
metal cycloaddition reactions / acyl metal / metal alkynes / metal-alkynyl bond / metal carbyne / stable metal carbene / stable metal species / reactive alkenyl metal / side chain / e- species / reductive elimination product / metal vinylidenes / /
Organization
CO NC / /
Person
Metal Alkylidene (Grubbs) / /
Position
rt / King / DMF/THF rt / /
Product
Metallacyclopentene Formation vs. Metal Vinylidene Formation / /