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Temperature Effects on Nickel Sorption Kinetics at the Mineral–Water Interface Kirk G. Scheckel* and Donald L. Sparks ABSTRACT spectroscopic and microscopic investigations, determination of basic thermodynamic and kine
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Document Date: 2001-06-27 08:35:21


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metal precipitation / energy barrier / chemical safety / multinuclear metal-ion complexes / mixed metal / metal adsorption kinetics / stable metal precipitates / metal oxides / less energy requirements / free energy / pure metal hydroxide phase / metal sorption kinetics / energy barrier increases / metal carbonate / heterogeneous systems / metal refineries / chemical reaction processes / metal precipitation reactions / metal surface / aqueous solution / parabolic rate law / metal sorption / metal uptake / energy / elementary solution / chemical reactions / mineral systems / Activation energy values / reactive site / thermodynamic solubility product / pure and mixed systems / layered singleand double-metal hydroxide precipitates / gas constant / energy requirement / heavy metal / metal precipitates / potential energy surface / Chemical kinetics / aqueous solutions / typical metal-sorption behavior / soil chemical processes / activation energy / metal hydroxide precipitates / metal hydroxides / /

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World Health Organization / Univ. of Delaware / USDA / National Risk Management Research Lab. / Environmental Protection Agency / /

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Donald L. Sparks / C.J. Chisholm-Brause / S.N. Towle / Kirk G. Scheckel / J.R. Bargar / Trivedi / G.E. Brown / Jr. / Barrow / G.A. Parks / Svante Arrhenius / /

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Ae⫺Ea/RT / Ea/RT / RT / H‡/RT / diffusion model / linear-isotherm model / ⌬G‡/RT / physical chemist / different diffusion model / /

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x-ray / Sorption / ion exchange / Thermodynamics / spectroscopy / dialysis / /

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