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Materials science / Spectroscopy / Condensed matter physics / Environmental chemistry / XANES / Extended X-ray absorption fine structure / Adsorption / X-ray absorption fine structure / Astronomical spectroscopy / Chemistry / Science / Scientific method


Article pubs.acs.org/JACS Probing Adsorption Interactions in Metal−Organic Frameworks using X‑ray Spectroscopy Walter S. Drisdell,† Roberta Poloni,†,‡,§,∥ Thomas M. McDonald,†,§ Jeffrey R. Long,†,§ Be
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Document Date: 2013-12-06 13:35:03


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Kunz / New York / /

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BP / Clean Energy Technologies / McDermott / Furukawa / Lawrence Berkeley National Laboratory / Simmons / ASSOCIATED CONTENT / /

Country

France / United States / United Kingdom / /

Currency

pence / /

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Facility

Molecular Foundry / University of California / /

IndustryTerm

gas adsorptionincluding / lower-energy spectral features / gas present / gas molecules / photon energy / gas uptake / dry gas mixtures / low-energy transitions / energy calibration / low-energy transition / gas-phase measurements / high-energy transition / unoccupied apical site / gas absorption / meaningful energy differences / gas cell / metal−adsorbate binding strength / different systems / lower energy / lowest energy excitations / gas cell design / in situ gas / condensed-phase systems / open metal site / energy differences / energy / metal / chemical specificity / metal site / gas pressures / gas adsorption / five-coordinate metal cations / gas pressure / higher-energy features / distinct open metal sites / gas inlet / designed gas cell / higher energy / fundamental gas interaction mechanisms / open metal sites / low-energy / low-energy states / sharp low-energy spectral feature / metal sites / larger binding energy / apical site / gas separation / /

OperatingSystem

Fermi / /

Organization

U.S. Department of Energy / University of California / Berkeley / Department of Chemistry / American Chemical Society / Energy Frontier Research Center / /

Person

David Prendergast / Thomas M. McDonald / Gale / Lewis acidsare / Hudson / Walter S. Drisdell / † Roberta / Roberta Poloni / /

Position

Queen / AUTHOR / Corresponding Author jbkortright@lbl.gov Author / representative / /

Product

Mg atom / Mg 1s / Mg 3p / Mg 3s / /

ProvinceOrState

California / A. B. / /

Technology

X-ray / hybridization / Spectroscopy / /

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http /

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