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Organic chemistry / Organocatalysis / Nucleophilic conjugate addition / Michael reaction / Carbonyl / Carbon–hydrogen bond activation / Alkylation / Aldol reaction / Chemistry / Organic reactions / Catalysis


Communication pubs.acs.org/JACS Direct β‑Alkylation of Aldehydes via Photoredox Organocatalysis Jack A. Terrett, Michael D. Clift, and David W. C. MacMillan* Merck Center for Catalysis, Princeton University, Princeton
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Document Date: 2014-06-30 08:53:29

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City

Weinheim / Kano / New York / /

Company

Merck / Kubota / Amgen / Ge / MacMillan / Allen A. E. / ASSOCIATED CONTENT / /

Country

United States / /

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Facility

Princeton University / IrIII complex / /

IndustryTerm

β-alkylation protocol / desired β-alkylated product / terminal methyl site / aldehyde α-alkylation products / chemical transformation / proposed β-alkylation protocol / β-alkylated product / methyl ester systems / β-aryl carbonyl products / described intermolecular βalkylation protocol / desired β-alkylation product / functionalization protocol / β-unsaturated systems / chemical methods / /

Organization

American Chemical Society / David W. C. MacMillan* Merck Center for Catalysis / Princeton University / /

Person

Renaud / V / Michael D. Clift / Jack A. Terrett / /

Position

V. P. / Communication AUTHOR INFORMATION Corresponding Author dmacmill@princeton.edu Notes The authors / /

ProvinceOrState

New Jersey / /

PublishedMedium

Journal of the American Chemical Society / /

Technology

proposed β-alkylation protocol / β-alkylation protocol / described intermolecular βalkylation protocol / condensation / redox-neutral / atom-economical C−H functionalization protocol / spectroscopy / /

URL

http /

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